Friday, 27 February 2004
Safety:
While epoxy is a much safer
material than many other products used in boat building, some handling precautions
should be taken. Epoxy should be stored in a safe manner, so that anyone, especially
children cannot ingest it or get it on their skin.
Most people, even
those who frequently work with epoxy do not have any health problems associated
with epoxy use. A small number of users can, over time, develop some skin sensitivity.
This is basically an allergic reaction and has no other consequence. The best
way to avoid that allergy is to wear gloves and avoid contact between uncured
resin and the skin.
It is recommended
to use eye and skin protection at all times when handling epoxy. In case of
contact, do not use chemical solvents to remove epoxy from your skin. Plain
white vinegar will remove spots and spills.
Uncured epoxy resin and hardener is considered hazardous material, and must
be disposed of in an approved manner. Epoxy resin and hardener have a very low
flammability, but keep in mind that in a boat building workshop, many of the
thinning and cleanup solvents such as acetone are flammable and explosive. Keep
your mind on the job. See a physician if any health problems develop.
What is epoxy?
Epoxy is an extremely
tough and durable synthetic resin. It differs from other resins used in boat
building. Epoxy bonds much better than polyester or vinylester, has superior
mechanical characteristics and has a much better resistance to chemicals, water
etc.

Epoxy resin,
like polyester, is produced by a chemical reaction between two components. Polyester
cures (harden) when a small amount of catalyst is added but epoxy cures after
mixing relatively large amounts of hardener and resin. Epoxy is the result of
the cross-linking between molecules of hardener and resin. The two components
combine with each other and the cure of the resin does not produce any residues.
When polyester cures, styrene (a gas) is released and creates that characteristic
unpleasant smell. Epoxy doesn't smell or only very little.
In boat building
applications, epoxy can be used as glue, putty or as a fiberglass laminating
resin. In high tech boat building or for larger boats, we may specify different
resins for different applications. Viscosity, strength, heat deflection and
other properties may vary. In all other cases, we will use a general-purpose
epoxy. Our general purpose marine epoxy resin has a low viscosity, wets the
fiberglass easily and shows mechanical and chemical characteristics far superior
to the polyester resins used in the production of fiberglass boats.
How to use
epoxy:
You will never
use resin and hardener by themselves. The two components must always be mixed.
Our resin is mixed at a two to one ratio by volume: two volumes of resin and
one volume of hardener.
Do not
try to adjust the cure speed by using more hardener.
It will not work.
Quite the opposite, the resin will not cure.
This is very important: respect the two to one ratio.
How to measure:
We sell pumps
that fit on top of the jugs and you can pump two strokes of resin for each stroke
of hardener but the easiest way to measure is with a graduated cup.
If you do not
have a graduated cup, it is simple to make one.
Use plain clear
plastic cups. Fill one cup with water to a certain level: 1", 2", it doesn't
matter. Mark that level on the outside and mark the cup with an H for hardener.
This will be your hardener measuring cup.
Take another cup and using your hardener
cup, fill it with two times the measured volume of hardener. Mark the level
and mark the cup R for resin.
Now you have two cups with the exact ratio of 2:1 by volume.
(Dry your cups before using them, epoxy doesn't like to be mixed with water).
Beware of mixing
very small quantities of resin. The precision of your measurement will greatly
reduce, as the samples become smaller. You should not try to mix less than 2
oz. of resin and 1 oz. of hardener at a time.
Mix:
Mix the resin
and hardener thoroughly. Complete mixing is very important: mix each batch for one or two minutes. We use tongue depressors to mix but any stick will do. For
fiberglass lamination, use the resin without any filler but for use as a glue
or putty, different types of fillers must be added.
Epoxy glue:
We recommend
coating all wood surfaces with mixed epoxy resin before gluing. This is especially
important with large contact areas.
To make epoxy
glue is a two step process:
- Mix resin and hardener
- Add a filler to
the resin, in this case woodflour.

Add enough woodflour
to make a paste with the consistency of ketchup, usually 2 or 3 times the volume
of resin.
Gluing with epoxy
is different from using traditional wood glue. Epoxy is gap filling. It needs
a small gap to produce a good bond. Traditional wood glues require a tight fit
and high pressure. Epoxy requires a small gap and little pressure. You need
to keep a minimum of glue between the parts. If you press the epoxy glue out
of the assembly either because of a tight fit or too much pressure, the bond
may fail. When done properly, the epoxy glue bond is stronger than the parts.
Epoxy will not bond properly to a dirty or greasy surface. Clean the surface
before applying epoxy.
Let the resin
cure. Cure time varies with temperature and hardener speed. See the paragraph
about hardener further down.
Putty fillets:
In stitch and
glue and in composite boat building, parts of a boat are often assembled with
epoxy resin putty fillets.
The putty is made the same way than
glue but we use extra filler to obtain a thicker paste. The ideal viscosity
is similar to peanut butter.
Putty can be made with wood flour but the ideal filler is a mix of microballoons
and silica. Microballoons are microscopic bubbles of glass or plastic (phenolic).
Silica is some kind of chemically pure sand.

A mix of resin
and microballoons is very light and easy to sand, silica is very hard and difficult
to sand but silica is thixotropic. This means that it keeps the mixture from
sagging on vertical surfaces. Our filler mix contains the right proportions
of silica and microballoons, enough silica to keep it from running but not too
much for easy sanding.
Again, before applying a fillet, we recommend to pre coat the parts with unfilled
resin.
Often, the putty fillets are covered with one or several layers of fiberglass
for extra strength.
Fiberglass
lamination:
Fiberglass lamination
is the process by which you produce a fiberglass hull or boat part. In stitch
and glue boat building, plywood is covered with one or several layers of fiberglass
impregnated with resin. After the cure, this will produce a hard fiberglass
coating.
In composite boat building, the whole hull core made of plywood or foam is covered
with fiberglass and resin, inside and outside.
In production boats, the same process is used to make complete hulls or parts
in a mold.

Fiberglassing
is easy: a piece of fiberglass is wetted out with resin. The resin is applied
the same way that paint could be used, with a roller or a brush.
There are different types of fiberglass. The designer of your boat will specify
which one to use. Not all types of fiberglass are compatible with epoxy resin.
Some types of glass fabrics are made especially for use with polyester. They
use a binder that dissolves in styrene. Since there is no styrene in epoxy,
the binder will not allow epoxy resin to wet the fiberglass. Be certain that
you use fiberglass fabric compatible with epoxy.
Dry fiberglass is white but as the resin penetrates the fabric, it becomes transparent.
Do not use more resin than what is necessary to wet the glass.
A laminate with a high glass content will be stronger than one with too much
resin. Too much resin makes a laminate weaker, not stronger. Resin rich
is bad for strength and bad for your budget, do not waste resin.
For that reason,
as soon as the glass is wetted out (= transparent), squeeze the excess resin
out with a plastic spreader. Trained laminators push the resin through the glass
with squeegees or spreaders.
Hardener speeds
and post cure:
Epoxy resin can
cure (harden) faster or slower depending on the hardener you use. The trial
kit contains medium hardener, which is ideal in 80% of the cases.
The technical support web site bateau2.com shows a table with cure speeds. Fast
hardeners are useful when working in temperatures below 50 F (10 C) and slow
hardeners are for temperatures above 85 F (29 C).
Resin will cure faster in a cup than spread out on plywood or fiberglass. The
chemical reaction is exothermic. This means that it produces heat. A large mass
of resin in a cup will produce heat and cure much faster than resin spread in
thin coats. This "pot life" is the limiting factor when choosing hardener speed
or estimating the quantity to mix at one time. As an example, a small cup of
6 oz. of resin with medium hardener will have a pot life of around 25 minutes
at 70 F (21 C).
After that time, the resin will begin to "gel".
The next phase is called "green" resin. At that stage, the resin is hard like
firm cheese but has still no strength. Excess resin and glass can easily be
cut or removed at that stage with a sharp knife.
The hard cured stage comes much later: from a few hours to a few days depending
on the temperature. Again, with medium speed hardener, there will be no complete
cure until the temperature raise above 60 F (16C) for at least a few hours.
A post cure is always recommended: we like to roll our boat hulls out in the
sun for a day before sanding or painting.
Finish:
Boat hulls and
parts are usually sanded, faired with a fairing compound and painted. The fairing
compound is often epoxy resin with our mixed filler.
See our technical support web site bateau2.com for details. |